13.6 Estimate the total number of air molecules (inclusive of oxygen, nitrogen, water vapour and other constituents) in a room of capacity 25.0 m3 at a temperature of 27 °C and 1 atm pressure.

The volume of the room, V = 25.0 m3
Temperature of the room, T = 27°C = 300 K
Pressure in the room, P = 1 atm = 1 × 1.013 × 105 Pa
The ideal gas equation is:
PV = NkBT
Where kB = Boltzmann constant = 1.38 × x10-23 m2kg s-2K-1
The number of air molecules in the room is given by,
N=PVkBT=1.013×105×251.38×10-23×300= 6.11 × 1026 molecules
Therefore, the total number of air molecules in the given room is 6.11 × 1026