The first ionisation enthalpies of Na, Mg, Al, and Si are in the order of:

1. Na < Al < Mg < Si

2. Na > Mg > Al > Si

3. Na < Mg < Al < Si

4. Na > Mg > Al < Si

HINT: Left to right across the period ionisation enthalpy increases.
Explanation:
Follow the following steps to solve out such problems

Steps

Method

Apply

Step I

Write the electronic configuration to find position in the periodic table

Na11=[Ne]3s1, Mg12=[Ne]3s2
Al13=[Ne]3s23p1, Si14=[Ne]3s23p2

Step II

Arrange them in the order as they are in the periodic table

11  12 13 14
Na Mg Al  Si

Step III

Follow the general trend and also keep in mind the exception

The IP increases along a period from left to right but IP of Mg is higher than that of Al due to completely filled 3s orbital in Mg.

Step IV

On the above basis find the order

The order of IP is Na < Al < Mg < Si