Photochemical smog is formed as a result of the reaction of sunlight with hydrocarbons and nitrogen oxides. Ozone, nitric oxide, acrolein, formaldehyde, and peroxyacetyl nitrate (PAN) are common components of photochemical smog. The formation of photochemical
smog can be summarized as follows: Burning of fossil fuels leads to the emission of hydrocarbons and nitrogen dioxide in the atmosphere. High concentrations of these pollutants in air results in their interaction with
sunlight as follows:

                      $N{O}_{2\left(g\right)} \to N{O}_{\left(g\right)} + ·O_{\left(g\right)}$
$Nitrogen dioxide$
$·O_{\left(g\right)} + O_{2\left(g\right)}\to O_{3\left(g\right)}$
$O_{3\left(g\right)} + N{O}_{\left(g\right)} \to N{O}_{\left(g\right)} \to N{O}_{2\left(g\right)} + O_{2\left(g\right)}$
$$

While ozone is toxic in nature, both ${\mathrm{NO}}_2$ and ${\mathrm{O}}_3$ are oxidizing agents. They react with the unburnt hydrocarbons in air to produce formaldehyde, PAN, and acrolein.

                          $3C{H}_4+2O_3\to 3CH=O +3H_{2}O$