To get a n-type semiconductor from silicon, it should be doped with a substance with valency -

1.  2

2.  1

3.  3

4.  5

(4) HINT: In n-type semiconductor , electrons are charge carriers.
Explanation:
 To get a n-type semiconductor from silicon, it should be doped with a substance with valence 5.
e.g., Si doped with P lead to formation of n -type semiconductor as shown below :