The correct order of the packing efficiency in different types of unit cells is-

1.  Fcc < Bcc < Simple cubic

2.  Fcc > Bcc > Simple cubic

3.  Fcc < Bcc > Simple cubic

4.  Bcc < Fcc > Simple cubic

HINT: The packing efficiency is the fraction of the crystal (or unit cell) actually occupied by the atoms. FCC have highest packing fraction.
Explanation:
Packing efficiency in different types of unit cells can be tabulated as :

Unit cell

Packing efficiency

Fcc 

Bcc 

Simple cubic 

74%

68%

52%

Hence, correct orderis Fcc (74%) > Bcc (68%) > Simple cubic (62%).