Which of the following are peroxoacids of sulphur?

1. \(\mathrm{H_{2} SO_{5}  }  \text{ and }     \mathrm{H_{2} S_{2} O_{8}}\) 2. \(\mathrm{H_{2} SO_{5  }}   \text{ and }     \mathrm{H_{2} S_{2} O_{7}}\)
3. \(\mathrm{H_{2} S_{2} O_{7}}   \text{ and }     \mathrm{H_{2} S_{2} O_{8}}\) 4. \(\mathrm{H_{2} S_{2} O_{6}}   \text{ and }     \mathrm{H_{2} S_{2} O_{7}}\)

Hint: Peroxoacid contains -O-O- linkage.

 
Peroxoacids of sulphur must contain one -O-O- linkage.  H2SO5  and  H2S2O8 are the compound that contains a peroxy linkage. The structures of both the compound are as follows:
The structures of the other compounds are as follows: