Phenol is less acidic than:

1. Ethanol                          2.  o-Nitrophenol
3. o-Methylphenol              4.  o-Methoxyphenol

Hint: If electron withdrawing group attached to phenol then acidity of phenol increases.

In o-nitrophenol, nitro group is present at ortho position. Presence of electron withdrawing group at ortho position increases the acidic strength. On the other hand, in o-methylphenol and in o-methoxyphenol, electron releasing group(-CH3,-OCH3) are present.

Presence of these groups at ortho or para positions of phenol decreases the acidic strength of phenols. So, phenol is less acidic than o-nitrophenol.