Match the following reactants in Column I with the corresponding reaction products in Column II.

Column I

Column II

A. Benzene+Cl2AlCl3

1. Benzoic acid

B. Benzene+CH3ClAlCl3

2. Methyl phenyl ketone

C. Benzene+CH3COClAlCl3

3. Toluene

D. TolueneKMnO4/NaOH

4. Chlorobenzene

5. Benzene hexachloride

   

Options:  A   B   C   D 
1. 4  3  2  1 
2. 1 2 3 5
3. 5 4 3 2
4. 4 5 3 2


Hint: Electrophilic aromatic substitution reaction
The reaction is as follows:

Column I

Column II

A. Benzene+Cl2AlCl3

Friedel Craft's reaction

B. Benzene+CH3ClAlCl3

Friedel Craft's alkylation reaction

Toluene

C. Benzene+CH3COClAlCl3

Methyl phenyl ketone (Friedel Craft's acetylation reaction)

D. TolueneKMnO4/NaOH

Oxidation reaction

Benzoic acid