Match the items given in Column I and Column II.

Column I Column II
A. Protective colloid 1. FeCl3 + NaOH
B. Liquid-liquid colloid 2. Lyophilic colloids
C. Positively charged colloid 3. Emulsion
D. Negatively charged colloid 4. FeCl+ hot water

Codes

A B C D
1. 3 2 4 1
2. 1 4 3 2
3. 2 3 4 1
4. 4 1 3 2

Hint: When ferric chloride is added to NaOH solution a negatively charged sol is obtained with adsorption of OHions.

The protective colloid is a type of lyophilic (water-loving) colloid that is used to protect the lyophobic colloids from precipitating in an electrolytic solution.

An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation.

If FeCl3 is added to the excess of hot water, a positively charged sol of hydrated ferric oxide is formed due to the adsorption of Fe3+ ions.

When ferric chloride is added to NaOH solution a negatively charged sol is obtained with adsorption of OHions.

hence, option third is the correct answer.